A fluidized bed reactor (FBR) is a type of reactor device that can be used to carry out a variety of multiphase chemical reactions. In this type of reactor, a fluid (gas or liquid) is passed through a granular solid material (usually a catalyst possibly shaped as tiny spheres) at high enough velocities to suspend the solid and cause it to behave as though it were a fluid. This process, known as fluidization, imparts many important advantages to the FBR. As a result, the fluidized bed reactor is now used in many industrial applications. Basic principles
The solid substrate (the catalytic
material upon which chemical species react) material in the fluidized bed
reactor is typically supported by a porous plate, known
as a distributor.
The fluid is then forced through the distributor up through the solid material.
At lower fluid velocities, the solids remain in place as the fluid passes
through the voids in the material. This is known as a packed bed
reactor. As the fluid velocity is increased, the reactor will reach a stage
where the force of the fluid on the solids is enough to balance the weight of
the solid material. This stage is known as incipient fluidization and occurs at
this minimum fluidization velocity. Once this minimum velocity is surpassed,
the contents of the reactor bed begin to expand and swirl around much like an
agitated tank or boiling pot of water. The reactor is now a fluidized bed.
Depending on the operating conditions and properties of solid phase various
flow regimes can be observed in this reactor.
History
and current uses
Fluidized bed reactors are a
relatively new tool in the chemical engineering field. The first fluidized bed
gas generator was developed by Fritz Winkler in Germany in the 1920s.
One of the first United States fluidized bed reactors used in the petroleum
industry was the Catalytic Cracking Unit, created in Baton Rouge, LA in 1942
This FBR and the many to follow were developed for the oil and petrochemical
industries. Here catalysts were used to reduce petroleum to simpler
compounds through a process known as cracking. The invention of this technology
made it possible to significantly increase the production of various fuels in
the United States.
In the late 1980s, the work of Gordana V. Novakovic, Robert
S. Langer, V.A. Shiva Ayyadurai and others began the use of
fluidized bed reactors in biological sciences for understanding and visualizing the fluid
dynamics of blood deheparinization.
Today fluidized bed reactors are
still used to produce gasoline and other fuels, along with many other
chemicals. Many industrially produced polymers are
made using FBR technology, such as rubber, vinyl chloride, polyethylene,
styrenes,
and polypropylene.
Various utilities also use FBR's for coal
gasification, nuclear power plants, and water and waste treatment settings.
Used in these applications, fluidized bed reactors allow for a cleaner, more
efficient process than previous standard reactor technologies.
Advantages
The increase in fluidized bed
reactor use in today's industrial world is largely due to the inherent
advantages of the technology.
- Uniform Particle Mixing: Due to the intrinsic fluid-like behavior of the solid material, fluidized beds do not experience poor mixing as in packed beds. This complete mixing allows for a uniform product that can often be hard to achieve in other reactor designs. The elimination of radial and axial concentration gradients also allows for better fluid-solid contact, which is essential for reaction efficiency and quality.
- Uniform Temperature Gradients: Many chemical reactions require the addition or removal of heat. Local hot or cold spots within the reaction bed, often a problem in packed beds, are avoided in a fluidized situation such as an FBR. In other reactor types, these local temperature differences, especially hotspots, can result in product degradation. Thus FBRs are well suited to exothermic reactions. Researchers have also learned that the bed-to-surface heat transfer coefficients for FBRs are high.
- Ability to Operate Reactor in Continuous State: The fluidized bed nature of these reactors allows for the ability to continuously withdraw product and introduce new reactants into the reaction vessel. Operating at a continuous process state allows manufacturers to produce their various products more efficiently due to the removal of startup conditions in batch processes
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